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Hoy es el día más hermoso de nuestra vida, querido Sancho; los obstáculos más grandes, nuestras propias indecisiones; nuestro enemigo más fuerte, el miedo al poderoso y a nosotros mismos; la cosa más fácil, equivocarnos; la más destructiva, la mentira y el egoísmo; la peor derrota, el desaliento; los defectos más peligrosos, la soberbia y el rencor; las sensaciones más gratas, la buena conciencia, el esfuerzo para ser mejores sin ser perfectos, y sobretodo, la disposición para hacer el bien y combatir la injusticia dondequiera que esté.

MIGUEL DE CERVANTES
Don Quijote de la Mancha.

15 de mayo de 2018

The photoexcited graphene puzzle solved

by Staff WritersMadrid, Spain (SPX) May 15, 2018

Schematic representation of the ultrafast optical pump - terahertz probe experiment, where the optical pump induces electron heating and the terahertz pulse is sensitive to the conductivity of graphene directly after this heating process, which occurs on a timescale faster than a millionth of a millionth of a second.
Light detection and control lies at the heart of many modern device applications, such as the camera you have in your phone. Using graphene as a light-sensitive material for light detectors can offer significant improvements with respect to materials being used nowadays.
For example, graphene can detect light of almost any colour, and it gives an extremely fast electronic response within one millionth of a millionth of a second. Thus, in order to properly design graphene-based light detectors it is crucial to understand the processes that take place inside the graphene after it absorbs light.
A team of European scientists including ICFO from Barcelona (Spain), IIT from Genova (Italy), the University of Exeter from Exeter (UK) and Johannes Gutenberg University from Mainz (Germany), have now succeeded in understanding these processes.
Published recently in Science Advances, their work gives a thorough explanation of why, in some cases, the graphene conductivity increases after light absorption and in other cases, it decreases.
The researchers show that this behaviour correlates with the way in which energy from absorbed light flows to the graphene electrons: After light is absorbed by the graphene, the processes through which graphene electrons heat up happen extremely fast and with a very high efficiency.
For highly doped graphene (where many free electrons are present), ultrafast electron heating leads to carriers with elevated energy - hot carriers - which, in turn, leads to a decrease in conductivity.
Interestingly enough, for weakly doped graphene (where not so many free electrons are present), electron heating leads to the creation of additional free electrons, and therefore an increase in conductivity. These additional carriers are the direct result of the gapless nature of graphene - in gapped materials, electron heating does not lead to additional free carriers.
This simple scenario of light-induced electron heating in graphene can explain many observed effects. Aside from describing the conductive properties of the material after light absorption, it can explain carrier multiplication, where - under specific conditions - one absorbed light particle (photon) can indirectly generate more than one additional free electron, and thus create an efficient photoresponse within a device.
The results of the paper, in particular, understanding electron heating processes accurately, will definitely mean a great boost in the design and development of graphene-based light detection technology.

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